2.2 Mold surface strengthening heat treatment
Mold surface strengthening treatment process mainly has gas nitriding method, ion nitriding method, spark surface strengthening method, boron penetration, TD method, CVD method, PVD method, laser surface strengthening method, ion injection method, plasma spraying method and so on.
① Gas nitrocarburizing: Nitrogen is decomposed at nitriding temperature to produce active nitrogen atoms, which are absorbed by the metal surface and infiltrated into the steel and continuously diffuse from the surface to the inside to form a nitrided layer. After nitriding treatment, the surface hardness of the mold can reach HV950~1200, which makes the mold have high red hardness and high fatigue strength, and improves the degree of surface finish of the mold and resistance to occlusion.
② ion nitriding: the mold to be treated in a vacuum container, filled with a certain pressure of nitrogen-containing gases (such as nitrogen or nitrogen, hydrogen mixture), and then the mold to be treated as the cathode to the cover wall of the vacuum container as the anode, in the cathode and anode plus 400 to 600 volts of DC voltage, the cathode and anode will produce a glow discharge between the container of the gas is ionized in space to produce a large number of electrons and ions. Under the action of the electric field, positive ions rushed to the cathode, with a very high speed bombardment of the mold surface, the mold heating. Ion energy positive ions rushed into the mold surface, access to electrons, into nitrogen atoms are absorbed by the mold surface, and inward diffusion to form a nitrided layer. Application of ion nitriding method can improve the wear resistance and fatigue strength of the mold.
③ ignition surface strengthening: this is a direct use of electrical energy, high energy density of the mold surface strengthening process. It is through the role of spark discharge, as the electrode of the conductive material dissolved into the surface layer of the metal workpiece, thus forming an alloyed surface strengthening layer, so that the physical and chemical properties of the work surface and mechanical properties have been improved. For example, the use of WC, TiC and other cemented carbide electrode materials to strengthen the surface of high-speed steel or alloy tool steel, can form a micro-hardness of HV1100 or more wear-resistant, corrosion-resistant and red-hard reinforced layer, so that the service life of the mold has been significantly improved. Spark surface strengthening of the advantages of simple equipment, easy to operate, after treatment of the mold wear resistance to improve significantly; disadvantages are the strengthening of the surface is rougher, the thickness of the strengthening layer is thinner, strengthen the processing of low efficiency.
④ boron: boron layer has good red hardness, wear resistance, boron can significantly improve the surface hardness of the mold (up to HV1300 ~ 2000) and abrasion resistance, can be widely used in mold surface strengthening, especially suitable for dealing with abrasive wear conditions in the mold. But the boron layer tends to exist a greater brittleness, which also limits its application.
⑤ TD heat treatment: put a heat-resistant steel crucible in the air furnace or salt bath, put borax into the crucible and heat and melt it to 800℃~1200℃, and then add the corresponding carbide forming powder (such as titanium, barium, niobium, chromium), and then put the steel or cemented carbide workpiece into crucible and dip and keep warm for 1~2 hours, and then add the element to diffuse to the surface of the workpiece and react with the carbon of the steel to form the carbide layer, and the obtained carbide layer has a very high quality, especially suitable for dealing with molds under the condition of abrasive wear. The obtained carbide layer has high hardness and wear resistance.
⑥ CVD method (chemical vapor deposition): the mold will be placed in hydrogen (or other protective gases) heated to 900 ° C ~ 1200 ° C, after which the carrier gas, low-temperature gasification of volatile metal compounds gases such as titanium tetrachloride (TiCI4) and toluene CH4 (or other hydrocarbons) vapors brought into the furnace, so that the titanium and hydrocarbons in TiCI4 in the carbon (as well as the steel surface of the carbon fraction) Chemical reaction on the surface of the mold to produce a layer of the desired metal compound coating (e.g., titanium carbide).
⑦ PVD (Physical Vapor Deposition): The metal atoms used for reinforcement are evaporated in a vacuum chamber or bombarded with energy-charged particles, which are attracted and deposited onto the surface of the workpiece to form a chemical layer under the action of a current bias. The use of PVD penalties can be deposited on the surface of the workpiece titanium carbide, titanium nitride, aluminum oxide and other compounds.
⑧ laser surface strengthening: when a certain power of the laser beam to a certain scanning speed irradiation to the blackened surface of the mold, will make the mold surface in a very short period of time due to the absorption of laser energy and rapid warming. When the laser beam is removed, the mold work surface by the substrate itself conduction and rapid cooling, thus forming a certain performance of the surface of the reinforced layer, its hardness can be increased by 15 ~ 20%, in addition to the quenching group of small, wear-resistant, energy-saving effect is remarkable and can improve the working conditions and other advantages.
⑨ Ion injection: the use of small low-energy ion gas pedal, the need to inject the element of atoms, ionization into ions in the heater's ion source, and then through the ion heater's high-voltage electric field will be heated to become a high-speed ion stream, and then after the refining of the magnetic analyzer, ion beams will be forced into the mold placed in the target chamber of the mold work surface, thereby changing the mold surface micro-hardness and roughness, reduce the surface friction coefficient The service life of the mold will be improved eventually.
3 Mold machining process
Mold machining process is directly affect the service life of the mold and product quality is an important link. Because the shape of the mold parts are varied and high precision requirements, so in the processing in addition to the use of lathes, milling machines, planers, spade and grinders and other common machining equipment, but also need to apply a variety of advanced equipment, such as spark processing machine tools, spark wire cutting machine tools and precision grinding machine tools and so on. At present, for the complex structure and process requirements of special molds, a new type of processing methods different from the traditional machining - mold special processing (electroprocessing) has also been the rapid development.